Yellow and orange were hidden all summer
Carotenoid pigments are present year-round but masked by green chlorophyll until autumn.
Nature & Biology
Leaves do not suddenly invent yellow and orange in autumn. Those colors were mostly there already, hidden until chlorophyll breaks down.
Leaves are green in summer because they are packed with chlorophyll, the molecule that absorbs sunlight for photosynthesis. Chlorophyll reflects green light, which is what you see. Yellow and orange pigments were in many leaves the whole time, hidden by the stronger green. In autumn, shorter days and cooler temperatures signal trees to shut down their leaves. Without fresh chlorophyll being produced, existing chlorophyll breaks down and the green fades. The yellow and orange carotenoids are more stable and become visible. Red is different. Red anthocyanin pigment is produced fresh in autumn when sugars become trapped in the leaf. Warm sunny days and cool nights create the brightest reds because they promote sugar accumulation and anthocyanin production.

Yellow and orange were hidden all summer
Carotenoid pigments are present year-round but masked by green chlorophyll until autumn.
Red is made fresh in autumn
Anthocyanins that cause red and purple color form from trapped sugars in cool, bright conditions.
Myth: cold temperatures cause the color change
Cold affects intensity, but shorter day length is the main seasonal trigger.
Why some years are more colorful
Warm sunny days and cool but not freezing nights produce the strongest autumn color.
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